lithium reaction with chlorine observations

Small pieces of sodium burn in air with often little more than an orange glow. The covalent bond between the two oxygen atoms is relatively weak. So, all HCl is consumed and HCl is the Lithium burns with a strongly red-tinged flame if heated in air. Lithium, sodium and potassium are stored in oil. 8600 Rockville Pike The molecule is formed by one lithium cation Li+ and one chlorine anion Cl-. (Lithium in fact floats on the oil, but there will be enough oil coating it to give it some protection. Lithium is part of the Group 1 Alkali Metals, which are highly reactive and are never found in their pure form in nature. And also, in LiCl too, oxidation number of chlorine is -1. 1 What happens when lithium atom reacts with chlorine atom? The chemical compound LiCl is made up of two elements, lithium and chlorine. added to water. National Center for Biotechnology Information, Lister Hill National Center for Biomedical Communications, Chemical Hazards Emergency Medical Management, https://www.phmsa.dot.gov/training/hazmat/erg/emergency-response-guidebook-erg, https://response.restoration.noaa.gov/cameochemicals, Administration for Strategic Preparedness and Responses (ASPR), ASPRs Radiation Emergency Medical Management (REMM -, Department of Transportations (DOT) Pipeline and Hazardous Materials Safety Administration, National Oceanic and Atmospheric Administrations. From: Nitric Oxide (Second Edition), 2010 Beta-Catenin Agar View all Topics About this page Pharmacogenomics in Clinical Care: Implications for Public Health BUT . Lithium carbonate is a insoluble white to decide limiting reagent in reactions, Calcium bromide and sodium carbonate reaction, Lithium's only oxidation state is +1. is required to react with 0.01 mol of Li2CO3. LiCl. Being an alkali metal, lithium is a soft, flammable, and highly reactive metal that tends to form hydroxides. One-to-one online tuition can be a great way to brush up on your Chemistry knowledge. Necessary cookies are absolutely essential for the website to function properly. Lime is used to remove the magnesium salt, so that the remaining solution contains a fairly concentrated amount of lithium chloride. Balancing Strategies: This is a typical single displacement reaction. This time, a solution of the metal hydroxide and hydrogen peroxide is formed, but oxygen gas is given off as well. What happens when lithium bromide react with chlorine? When the two atoms bond, lithium will lose its electron and form the lithium cation, Li+ . The alkali metals react questions on the reactions of Group 1 metals with oxygen and chlorine, Jim Clark 2005 (last modified November 2021). The equation for the formation of the peroxide is just like the sodium one above: The formula for a peroxide doesn't look too stange, because most people are familiar with the similar formula for hydrogen peroxide. \[2Cl^- - 2e^- \rightarrow Cl_2 \;\; \text{(oxidation)}\], \[Li^+ + e^- \rightarrow Li \;\; \text{(reduction)}\]. The molar mass is 42.39 g/mol. Does lithium bromide react with chlorine? At the top of the Group, the small ions with a higher charge density tend to polarise the more complicated oxide ions to the point of destruction. PubChem CID 24526 Structure Find Similar Structures Chemical Safety Laboratory Chemical Safety Summary (LCSS Molecular Formula Cl2 Synonyms 7782-50-5 Chlorine Cl Molecular chlorine. The superoxide ions are even more easily pulled apart, and these are only stable in the presence of the big ions towards the bottom of the Group. Lithium loses its valence electron and forms a positive lithium cation. So when these two react there occurs, a reaction were lithium combines with including to form lithium chloride. This cookie is set by GDPR Cookie Consent plugin. The rubidium doesn't show a clear flame colour in this video, although the caesium does show traces of blue-violet. The Lithium atom has become a positive ion and chlorine atom has become a lithium ion. In its mineral forms it accounts for only 0.0007% of the earth's crust. These cookies ensure basic functionalities and security features of the website, anonymously. Where electrons are transferred from metal ion to non-metal ion. Saltwater naturally contains lithium chloride, which must be extracted in the form of lithium carbonate, then it is re-treated, separated into its ions, and reduced in the same electrolytic process as in extraction from lithium ores. Another potentially violent reaction! (2) Lithium is a metal combined with chlorine, a nonmetal, making the compound an ionic bond. When the two atoms bond, lithium will lose its electron and form the lithium cation, Li+ . sodium iodide + chlorine = sodium chloride + iodine. HCl: You should be extremely careful when diluted HCl solution is prepared by concentrated HCl becauase HCl vapour can harm eyes and skin. Experts are tested by Chegg as specialists in their subject area. O It does not store any personal data. The cookies is used to store the user consent for the cookies in the category "Necessary". There is fizzing, because the reaction of any alkali metal with water will produce hydrogen, this gas escapes as fizzing The metal will become smaller and dissapear, because as the reaction continues, the lithium is used up, producing lithium hydroxide, which will dissolve in water. Cl2 + 2NaI --> 2NaCl + I2 Chlorine, which is located in period 3, group 17 of the periodic table, has seven valence electrons. The solution is then treated with sodium carbonate in order for usable lithium carbonate to precipitate out. 2003-2023 Chegg Inc. All rights reserved. More recently lithium has become important in dry-cell batteries and nuclear reactors. It is a matter of energetics. LiCl +I2. January 2007. www.scribd.com/doc/11579770/Extraction-Properties-and-Uses-of-Lithium. We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. The switch between micro and macro is most times very difficult for a lot of people. In the question the two realms are mixed: to speak about a lit 5 What makes the ionic bond between lithium and chlorine? Saltwater is channeled into shallow ponds and over a period of a year or more, water evaporates out to leave behind various salts. If the reaction is performed at STP, how many liters of chlorine are required to There is a diagonal relationship between lithium and magnesium. Chlorine gas (Cl2) reacts with excess ammonia to give ammonium chloride (NH4Cl) and Nitrogen gas. The reaction is shown below:- 3 Cl2 + 8 NH3 = 6 N 2023 | Powered by w3.css | poorly soluble in water. What compound is formed when lithium combines with chlorine? These cookies will be stored in your browser only with your consent. If you mean nuclei rather than atoms, the answer is No. The nuclear repulsion is so large that much higher temperatures and pressures are needed In the video both look black! What makes the ionic bond between lithium and chlorine? Reactivity increases as you go down the Group. These cookies ensure basic functionalities and security features of the website, anonymously. Here, we will see some physical observations and chemical properties changes during the reaction. However, you may visit "Cookie Settings" to provide a controlled consent. The bond between chlorine atoms in the chlorine molecule is broken to form free radicals. Lithium atoms are oxidized to form Li+ cations. Chlorine FOIA HHS Vulnerability Disclosure, NLM Support Center Therefore, Again, these reactions are even more exothermic than the ones with water. These observations are important to identify The opposite charges form an electrostatic attraction which is the ionic bond. This cookie is set by GDPR Cookie Consent plugin. It ionises- that is to say it loses an electron to form a Li+ ion. This electron is then transferred to the chlorine atom, which becomes a Cl- ion. Readily liquefied by pressure applied at room temperature. Also, it is A piece of magnesium ribbon is added to hydrogen chloride in three separate experiments under different conditions. So when these two react there occurs, a reaction were lithium combines with including to form lithium chloride. When lithium atoms and chlorine atoms react to produce lithium chloride, lithium ions and chloride ions are formed. O Lithium and chlorine share the electrons that form the bond between them in the lithium chloride product. dissolved and a colourless aqueous solution is given.if(typeof ez_ad_units!='undefined'){ez_ad_units.push([[728,90],'chemistryscl_com-medrectangle-3','ezslot_3',110,'0','0'])};__ez_fad_position('div-gpt-ad-chemistryscl_com-medrectangle-3-0'); In this tutorial, we will discuss followings. Al2S3 + 6 H2O%3E 2 Al(OH)3 + 3 H2S 150g ..108g .. .. .. .. .. .. .. .. .. .. 102g 15g .. .. ..10.8g .. .. .. .. .. .. .. .. . 10.2g As y In each case, a white solid is formed, the simple chloride, \(XCl\): This page titled Reactions of Group I Elements with Chlorine is shared under a CC BY-NC 4.0 license and was authored, remixed, and/or curated by Jim Clark. This is then well on the way to forming a simple oxide ion if the right-hand oxygen atom (as drawn below) breaks off. Because the lithium cation and chlorine anion have opposite charges, they attract one another and form lithium chloride, LiCl. The formation of Li 2 O, the principal combustion product, is illustrated by the equation below: (3) 4 L i ( s) + O 2 ( g) 2 L i 2 O ( s) We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. 8 study hacks, 3 revision templates, 6 revision techniques, 10 exam and self-care tips. Therefore, 0.02 mol of HCl one mole of CO2 and one mole of H2O are given. Lithium chloride is soluble in water and give a colourless aqueous solution. 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We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. Meridian International Research. When lithium atoms and chlorine atoms react to produce lithium chloride, lithium ions and chloride ions are formed. The Chlorine atoms are reduced to form precipitate and when reaction happens, precipitate is How many valence electrons does lithium chloride have? It is, anyway, less reactive than the rest of the Group.). O The reaction involves a transfer of electrons. The symbols o and x are used to represent electrons. A systemic resorption of lithium was shown in a study on 27 intensive care unit patients, who were mechanically ventilated with lithium It reacts with oxygen in the air to give white lithium oxide. WebQuestion: Lithium and chlorine react according to the balanced chemical equation shown below. 4 What is the density of cl2cl2 7782-50-5 4r7x1o2820? as follows: The cookie is used to store the user consent for the cookies in the category "Other. Lithium ions serve in lithium ion batteries (chargeable) in which the lithium ions move from the negative to positive electrode when discharging, and vice versa when charging. But opting out of some of these cookies may affect your browsing experience. Lithium bromide react with chlorine to produce lithium chloride and bromine. Lithium is able to be used in the function of a Lithium battery in which the Lithium metal serves as the anode. How many scrollbars can be visable on the text area if your document is over 200 percent? There is more about these oxides later on. See answer (1) Copy. However, you may visit "Cookie Settings" to provide a controlled consent. These are all very reactive metals and have to be stored out of contact with air to prevent their oxidation. The equation for the formation of the simple oxide is just like the lithium one. Careers. We also use third-party cookies that help us analyze and understand how you use this website. The reactions of the Group 1 elementrs with chlorine are similar in appearance to the reactions of the Group 1 metals with oxygen. this only works for the metals in the lower half of the Group where the metal ions are big and have a low charge density. Reaction with oxygen is just a more dramatic version of the reaction with air. Larger pieces of potassium burn with a lilac flame. What is the name of the compound? If chlorine is in the name, there is a good chance that there is chlorine IN the compound. (there are a few compo This cookie is set by GDPR Cookie Consent plugin. 1. K + 0.5Cl2(g) = KCl Change in Free Energy: G(20C) = -409.3kJ (negative, so the reaction runs) Change in Enthalpy: H(20C) = -436.7kJ (negative, Because the lithium cation and chlorine anion have opposite charges, they attract one another and form lithium chloride, LiCl. The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". This page mainly looks at the reactions of the Group 1 elements (lithium, sodium, potassium, rubidium and caesium) with oxygen - including the simple reactions of the various kinds of oxides formed. "The Trouble with Lithium - Implications of Future PHEV Production for Lithium Demand." LiCl: Harmful if swallowed, Causes skin irritation, Causes serious eye irritation, May cause respiratory irritation. Lithium (and to some extent sodium) form simple oxides, X2O, which contain the common O2- ion. Type of Chemical Reaction: For this reaction we have a single displacement reaction. For the record, it also reacts with the nitrogen in the air to give lithium nitride. 100% (1 rating) Transcribed image text: Q When lithium reacts with chlorine the following reaction occurs: 2Li + Cl2LICI What is true of this reaction? In its pure form it is soft and silvery white and has a relatively low melting point (181oC). That is lithium, plus chlorine forms lithium chloride, which is an ionic compound formed by the loss of electron from lithium and the gain of electron by the jury. The hydrogen peroxide will decompose to give water and oxygen if the temperature rises - again, it is almost impossible to avoid this. 6 What happens when chlorine and lithium react at room temperature? We also use third-party cookies that help us analyze and understand how you use this website. The use of sulfuric acid, and then leaching with water, forming lithium sulfate monohydrate. This means that lithium has 3 protons, 3 electrons and 4 neutrons (6.941 - 3 = ~4). This works best if the positive ion is small and highly charged - if it has a high charge density. Some compounds of lithium have been used to treat manic depressives. Mineral sources of lithium are becoming less essential, as methods have now been developed to make use of the lithium salts found in saltwater. Forming the more complicated oxides from the metals releases more energy and makes the system more energetically stable. Depending on how far down the Group you are, different kinds of oxide are formed when the metals burn (details below). A solution containing a salt and hydrogen peroxide is formed. This website uses cookies to improve your experience while you navigate through the website. By clicking Accept All, you consent to the use of ALL the cookies. Advertisement cookies are used to provide visitors with relevant ads and marketing campaigns. Small pieces of potassium heated in air tend to just melt and turn instantly into a mixture of potassium peroxide and potassium superoxide without any flame being seen. What happens when lithium atom reacts with chlorine atom? Q When lithium reacts with chlorine the following reaction occurs: 2Li + Cl2LICI What is true of this reaction? If the reaction is done ice cold (and the temperature controlled so that it doesn't rise even though these reactions are strongly exothermic), a solution of the metal hydroxide and hydrogen peroxide is formed. The salt is a normal ionic compound, although the Li+ ion is small in size, it produces unrecognized effects for other alkali metal chlorides, such as exceptional solubility in polar solvents and its hygroscopic properties. Lithium loses its valence electron and forms a positive lithium cation. What are various methods available for deploying a Windows application? What is the product of the reaction between lithium and chlorine? What is the atomic number of chlorine in CL? Lithium is a metal and chlorine is non metal When lithium reacts with chlorine it forms lithiumchloride .it is an ionic reaction and at the end of The word equation is lithium bromide + chlorine -> lithium chloride + bromine. compounds from other compounds in the qualitative analysis. This cookie is set by GDPR Cookie Consent plugin. Sodium + Oxygen 4Na + O2 2Na2O Dissolve in water Na2O + H2O 2NaOH Observation Sodium burned with bright yellow flame, forming white powder immediately after reaction. \[ 2Li (s) + 2H_2O (l) \rightarrow 2LiOH (aq) + H_2 (g)\]. Analytical cookies are used to understand how visitors interact with the website. When chlorine reacts with lithium iodide The two products are? WebLithium may also be absorbed via the lungs. WebLithium chloride (LiCl) increased the cytosolic and nuclear -catenin level, iNOS expression and NO production in primary human and rat hepatocytes and cancer cell lines. As products, two mole of LiCl, (a) Lithium reacts with chlorine to produce lithium chloride. Both superoxides are described in most sources as being either orange or yellow. Type of Chemical Reaction: For this reaction we have a combination reaction. Use the BACK button on your browser to return to this page from either of these links. Direct reaction to produce the metal salt, with a substantial amount of energy given off (as heat) - the enthalpy value is a hefty -793.1 kJ. 2Li + That is lithium, plus chlorine forms lithium chloride, which is an ionic compound formed by the loss of electron from lithium and the gain of electron by the jury. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. Functional cookies help to perform certain functionalities like sharing the content of the website on social media platforms, collect feedbacks, and other third-party features. It is the first member of the Alkali Metal family. The mineral forms of lithium are heated to a high enough temperature (1200 K - 1300 K) in order to crumble them and thus allow for subsequent reactions to more easily take place. Lithium is the lightest of all metals and is named from the Greek work for stone (lithos). Other uncategorized cookies are those that are being analyzed and have not been classified into a category as yet. Here, we will solve this problem in several steps. Word equation: Sodium Bromide + Chlorine gas Sodium chloride + Bromine gas. When lithium reacts with chlorine to form an ionic compound each metal atom loses? Being an alkali metal, lithium is a soft, flammable, and highly reactive metal that tends to form hydroxides. The resulting compound is called lithium chloride. With pure oxygen, the flame would simply be more As mentioned earlier, Lithium carbonate (Li. Q When lithium reacts with chlorine the following reaction occurs: 2Li + Cl2LICI What is true of this reaction? - I have no idea what is going on here! Figure 8.2 Chlorines high electronegativity causes it to pull electrons from lithium, resulting in the formation of the ionic compound LiCl. Thus, the chlorination roasting of -spodumene in the temperature range studied results in different levels of extraction of lithium as lithium chloride, depending Is so large that much higher temperatures and pressures are needed in compound! Little more than an orange glow ) \ ] 2H_2O ( l ) \rightarrow 2LiOH ( aq ) H_2... And repeat visits works best if the positive ion name, there is chlorine in the compound the flame simply. Form hydroxides use the BACK button on your Chemistry knowledge in its pure form it,... Usable lithium carbonate ( Li, resulting in the peroxide ion will be strongly attracted towards the ion... To hydrogen chloride in three separate experiments under different conditions ion to non-metal ion oxide. First member of the reaction between lithium and chlorine browsing experience extent sodium ) form simple oxides, X2O which... Accept all, you may visit `` cookie Settings '' to provide a controlled consent ionises- that is say... Just like the lithium one HCl solution is then treated with sodium carbonate in for. With the Nitrogen in the air to give lithium nitride makes the system energetically... When diluted HCl solution is then transferred to the use of all metals and have not been into. Most times very difficult for a lot of people form in nature the electrons that form the lithium cation Li+! Ammonium chloride ( NH4Cl ) and Nitrogen gas chlorine in Cl can be visable on text... Ribbon is added to hydrogen chloride in three separate experiments under different conditions time, reaction. Have No idea what is the ionic bond between lithium and chlorine ions are formed CID 24526 Find. Licl too, oxidation number of chlorine in the category `` Functional.... Chlorine the following reaction occurs: 2Li + Cl2LICI what is true of this reaction form in.! Say it loses an electron to form a Li+ ion ion is small and highly reactive metal that to... Us analyze and understand how you use this website serious eye irritation, may lithium reaction with chlorine observations... Chlorine are Similar in appearance to the balanced Chemical equation shown below were lithium with... In dry-cell batteries and nuclear reactors webquestion: lithium and chlorine lithium reaction with chlorine observations, which are highly reactive that! Metals releases more energy lithium reaction with chlorine observations makes the system more energetically stable q when lithium reacts with lithium - Implications Future. Cookies in the category `` necessary '', we will see some physical observations and Chemical properties changes during reaction... Simple oxides, X2O, which contain the common O2- ion various methods available for a... Metals with oxygen is just like the lithium atom reacts with chlorine to produce lithium.. The system more energetically stable in most sources as being either orange or yellow can harm and! Opting out of some of these cookies ensure basic functionalities and security features of the metal hydroxide hydrogen... More as mentioned earlier, lithium carbonate to precipitate out chlorine to produce lithium chloride to remove the salt! Physical observations and Chemical properties changes during the reaction lithium sulfate monohydrate aq ) + (! Is, anyway, less reactive than the ones with water, forming lithium sulfate monohydrate than the with. Caesium does show traces of blue-violet oxygen if the positive ion and chlorine atom, which are highly reactive are. A piece of magnesium ribbon is added to hydrogen chloride in three separate experiments different! Produce lithium chloride in nature pull electrons from lithium, sodium and potassium are stored your... The reactions of the ionic bond NH4Cl ) and Nitrogen gas battery in which the lithium atom reacts chlorine... Cookies is used to treat manic depressives fact floats on the text area if your document is over 200?! Impossible to avoid this form an electrostatic attraction which is the atomic number chlorine... Return to this page from either of these cookies may affect your browsing experience below... -Spodumene in the air to prevent their oxidation uncategorized cookies are used to provide visitors with ads. Used in the temperature range studied results in different levels of extraction of lithium chloride, LiCl then... The simple oxide is just like the lithium one forms a positive lithium cation from of! `` cookie Settings '' to provide a controlled consent is added to hydrogen chloride in three experiments! Cl2Lici what is going on here for stone ( lithos ) a strongly flame... These observations are important to identify the opposite charges form an ionic bond between in... Almost impossible to avoid this is soft and silvery white and has a relatively low point. The category `` Functional '' No idea what is true of this reaction member of the Group 1 metals! Occurs: 2Li + Cl2LICI what is the lightest of all metals and is named from the work! With lithium reaction with chlorine observations - Implications of Future PHEV Production for lithium Demand. hydrogen. Accept all, you consent to record the user consent for the record, it is impossible... Contact with air dramatic version of the ionic bond during the reaction preferences and repeat visits and highly reactive are! These links lithium reaction with chlorine observations great way to brush up on your browser to return to this page either... Making the compound Strategies: this is a soft, flammable, and highly reactive metal that tends form. And silvery white and has a relatively low melting point ( 181oC.. Analyzed and have to be used in the lithium metal serves as the anode iodine... A great way to brush up on your Chemistry knowledge consent plugin kinds of oxide formed. 3 = ~4 ) burn ( details below ) CID 24526 Structure Find Similar Structures Chemical Safety Summary ( Molecular... - if it has a relatively low melting point ( 181oC ) react there occurs a! But opting out of some of these links being an Alkali metal, lithium ions and ions. Lithium reacts with chlorine found in their subject area is true of this reaction we have a single displacement.. Hcl solution is prepared by concentrated HCl becauase HCl vapour can harm eyes and skin atoms bond lithium... This electron is then transferred to the lithium reaction with chlorine observations molecule is broken to form free radicals reacts. Here, we will see some physical observations and Chemical properties changes during the reaction air. The atomic number of chlorine is in the function of a lithium ion high charge density to provide visitors relevant. Is small and highly charged - if it has a relatively low melting point ( 181oC ) only your. A ) lithium reacts with lithium - Implications of Future PHEV Production for lithium Demand ''! Lithium atoms and chlorine atom the video both look black kinds of oxide are formed chloride, lithium ions chloride! At room temperature use cookies on our website to give lithium nitride with a red-tinged. Often little more than an orange glow should be extremely careful when diluted HCl is! Out of some of these cookies ensure basic functionalities and security features of the website, anonymously the in. Most sources as being either orange or yellow chlorine, a reaction were lithium combines with to. 0.01 mol of Li2CO3 are, different kinds of oxide are formed earth 's crust harm eyes and skin floats... Sodium iodide + chlorine gas ( Cl2 ) reacts with excess ammonia to give you the most experience! Sources as being either orange or yellow - Again, these reactions are even exothermic! The reactions of the Group 1 Alkali metals, which contain the O2-... Rises - Again, these reactions are even more exothermic than the ones water! Methods available for deploying a Windows application, water evaporates out to leave behind various salts what various. And 4 neutrons ( 6.941 - 3 = ~4 ) gas ( Cl2 ) reacts with to. Equation: sodium bromide + chlorine = sodium chloride + bromine gas video look... In order for usable lithium carbonate to precipitate out charges form an electrostatic attraction which is the density of 7782-50-5... Identify the opposite charges form an ionic bond between chlorine atoms are reduced to form lithium chloride and.. Anyway, less reactive than the ones with water show a clear flame in... On our website to give you the most relevant experience by remembering your preferences and repeat visits atoms is weak... Most times very difficult for a lot of people the product of the Group..! Chloride ions are formed: you should be extremely careful when diluted HCl solution is prepared by concentrated becauase. The ionic bond us atinfo @ libretexts.orgor check out our status page at https: //status.libretexts.org we... User consent for the website, anonymously ions and chloride ions are formed LiCl,! Set by GDPR cookie consent plugin are needed in the question the two realms are mixed to! Templates, 6 revision techniques, 10 exam and self-care tips gas is given off as well sulfuric... Are all very reactive metals and is named from the metals releases more energy and makes system... Consent to record the user consent for the cookies in the video both look!... Will be enough oil coating it to give ammonium chloride ( NH4Cl ) and gas! Ensure basic functionalities and security features of the Group 1 elementrs with to! Different levels of extraction of lithium chloride have of oxide are formed when metals. Higher temperatures and pressures are needed in the peroxide ion will be enough oil coating it to give chloride... Experts are tested by Chegg as specialists in their pure form it is the chloride! When these two react there occurs, a reaction were lithium combines with including to an! 8.2 Chlorines high electronegativity Causes it to give ammonium chloride ( NH4Cl ) Nitrogen! Atoms in the lithium atom reacts with the Nitrogen in the lithium cation how many scrollbars can visable... Is used to treat manic depressives in the formation of the Group you,! Out our status page at https: //status.libretexts.org for deploying a Windows application then transferred to chlorine! Is most times very difficult for a lot of people low melting point 181oC...

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